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PGZ .
Physikalische Gesellschaft Zürich
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PD Dr. Andreas Borgschulte
EMPA

The hydrogen anion: from astrophysics to solid hydrogen storage

Donnerstag 14. März 2024, um 19:30 Uhr
ETH Hauptgebäude Hörsaal HG G5, Rämistrasse 101 und Live Stream über Zoom (Link via e-Mail)

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If even the lord of the sky is interested on new insight in hydrogen storage in Mg, you may be interested as well (Andreas Borgschulte auf X)

The current state of energy transition is concerned with replacing fossil fuel energy conversion with renewable energy mainly based on electricity resulting in potential energy shortage ("Winterflaute"). Thus, ostensible goal is the highest conversion efficiency while neglecting other parameters such as scalability and tradability being more important in a developed renewable energy landscape.

Here, chemical fuels such as hydrogen have great potential. However, a high hydrogen storage density as pivotal for an energy carrier can only be reached by hydrogen storage in light weight metal hydrides. Despite huge research effort, practical implementation of such systems is still hampered by thermodynamic limitations.

In this talk, I will demonstrate along the archetypal example MgH2 that these limitations can be traced back to the intrinsic physical properties of the hydrogen in the material. Concretely, during absorption in Mg, hydrogen changes its chemical state from neutral to negative by forming the hydrogen anion. The peculiar properties of H-, which were first described by astrophysicists, need to be considered for further improvement of sorption kinetics in light weight metal hydrides.


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